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Abstract Temporal variations in lava chemistry at active submarine volcanoes are difficult to decipher due to the challenges of dating their eruptions. Here, we use high-precision measurements of 226Ra-230Th disequilibria in basalts from Kama‘ehuakanaloa (formerly Lō‘ihi) to estimate model ages for recent eruptions of this submarine Hawaiian pre-shield volcano. The ages range from ca. 0 to 2300 yr (excluding two much older samples) with at least five eruptions in the past ∼150 yr. Two snapshots of the magmatic evolution of Kama‘ehuakanaloa (or “Kama‘ehu”) are revealed. First, a long-term transition from alkalic to tholeiitic volcanism was nearly complete by ca. 2 ka. Second, a systematic short-term fluctuation in ratios of incompatible elements (e.g., Th/Yb) for summit lavas occurred on a time scale of ∼1200 yr. This is much longer than the ∼200-yr-long historical cycle in lava chemistry at the neighboring subaerial volcano, Kīlauea. The slower pace of the variation in lava chemistry at Kama‘ehu is most likely controlled by sluggish mantle upwelling on the margin of the Hawaiian plume. 

Shear localization in the upper mantle, a necessity for plate tectonics, can have a number of causes, including shear heating, the presence of melt, the development of a strong crystal preferred orientation, and the presence of water. The Josephine Peridotite of southwestern Oregon contains shear zones that provide an excellent opportunity to examine the initiation of shear localization. These shear zones are relatively small scale and low strain compared to many shear zones in peridotite massifs, which typically have extreme grain size reduction indicating extensive deformation. We use major, trace, and volatile element analyses of a large suite of harzburgites from the Fresno Bench shear zones to evaluate the mechanisms leading to shear localization. Lithological evidence and geochemical transects across three shear zones show a complex history of melting, melt addition, and melt‐rock interaction. The distribution of aluminum and heavy rare earth elements across the shear zones suggest that melt flow was focused in the centers of the studied shear zones. Water concentrations in orthopyroxene grains of 180–334 ppm H₂O indicate a comparatively high degree of hydration for nominally anhydrous minerals. The correlation of water with aluminum and ytterbium in orthopyroxene is consistent with a melt source for this hydration, suggesting that water equilibrated between the melt and peridotite. The presence of melt and hydration of the host rock provide mechanisms for initial weakening that lead to localized deformation.

 

Syntectonic microstructural evolution is a well‐known phenomenon in the mantle and lower crust associated with two main processes: grain size reduction through dynamic recrystallization and development of crystallographic preferred orientation (CPO). However, the effects of annealing via static recrystallization on grain size and CPO have been largely overlooked. We investigated mantle annealing by analyzing a suite of kimberlite‐hosted garnet peridotite xenoliths from the Wyoming Craton. We focus on five xenoliths that show microstructures reflecting different degrees of recrystallization, with annealed grains characterized by distinctive faceted boundaries crosscutting surrounding, nonfaceted matrix grains. These textures are indicative of discontinuous static recrystallization (DiSRX). Electron backscatter diffraction analysis further demonstrates a ∼10°–20° misorientation between DiSRXed grains and the matrix grains, resulting in an overall weaker CPO. These characteristics are remarkably similar to microstructures observed in samples that were annealed after deformation in the laboratory. Measurements of the thermal conditions and water contents associated with the last equilibration of the xenoliths suggests that high homologous temperatures (T/T_m > 0.9) are necessary to induce DiSRX. We postulate that annealing through DiSRX occurs under high temperatures after a short episode of intense deformation (years to hundreds of years) with timescales for annealing estimated as weeks to years, significantly slower than the timescale of hours expected for a kimberlitic magma ascent. We conclude that microstructural transformation due to DiSRX will occur during transient heating events associated with mantle upwelling, plumes, and lithospheric thinning.

 

The concentration of carbon in primary mid‐ocean ridge basalts (MORBs), and the associated fluxes of CO₂outgassed at ocean ridges, is examined through new data obtained by secondary ion mass spectrometry (SIMS) on 753 globally distributed MORB glasses. MORB glasses are typically 80–90% degassed of CO₂. We thus use the limited range in CO₂/Ba (81.3 ± 23) and CO₂/Rb (991 ± 129), derived from undegassed MORB and MORB melt inclusions, to estimate primary CO₂concentrations for ridges that have Ba and/or Rb data. When combined with quality‐controlled volatile‐element data from the literature (n = 2,446), these data constrain a range of primary CO₂abundances that vary from 104 ppm to 1.90 wt%. Segment‐scale data reveal a range in MORB magma flux varying by a factor of 440 (from 6.8 × 10⁵to 3.0 × 10⁸m³/year) and an integrated global MORB magma flux of 16.5 ± 1.6 km³/year. When combined with CO₂/Ba and CO₂/Rb‐derived primary magma CO₂abundances, the calculated segment‐scale CO₂fluxes vary by more than 3 orders of magnitude (3.3 × 10⁷to 4.0 × 10¹⁰mol/year) and sum to an integrated global MORB CO₂flux of × 10¹²mol/year. Variations in ridge CO₂fluxes have a muted effect on global climate; however, because the vast majority of CO₂degassed at ridges is dissolved into seawater and enters the marine bicarbonate cycle. MORB degassing would thus only contribute to long‐term variations in climate via degassing directly into the atmosphere in shallow‐water areas or where the ridge system is exposed above sea level.